In Steve’s latest Guest Blog he focuses on a few myths about flux cleaning
To begin, we clean and remove most flux residues to prevent metal oxidation and generally poor electronic circuit connections.
Technologists and technicians alike are often advised to clean boards post-soldering processes with isopropyl alcohol (i.e., IPA). But there are proven chemical reasons for not using a hygroscopic solvent like IPA (hygroscopic solvents draw moisture from the air to themselves as an equilibrium mechanism) for basic board cleaning and further process preparation.
In most instances, IPA is too aggressive for most plastics and can intrude into parts and spaces creating undesirable effects. IPA is known to dissolve polystyrene and other types of plastic capacitors. By dissolving various materials, a potential low-ohm and conductive film is spread over the surface of the PCB while the flux itself (typically a very high solids material) is left untouched in a host of board surface areas, and in particular, at the solder joints. Leftover flux materials can be detrimentally conductive in many instances.
A LOOK AT FLUX MATERIALSRosin-based flux is generally not conductive unless it is baked on at extremely high temperatures (caramel or black in color). Generally, no-clean flux is just that. It does not always require cleaning and you may leave it on. Many low-solids flux materials, when applied under a correctly controlled process, will completely evaporate with time. Most water-soluble fluxes need to be removed simply because they leave behind a soap-scum-like residue, which is generally conductive.
Additionally, there are some very aggressive fluxes like RA that must be removed as they contain very acidic substances. RMA is the most prevalent rosin flux (RMA rosin = mildly activated and RA rosin = less activated). It is actually not the rosin that performs the flux activity, but another substance in the flux compound, which promotes spreading and adhesion. The basic rosin material is simply a carrying vessel for the active flux ingredient.
FLUX WORKS ON TWO FRONTSWhen activated (and temperature controls this; most fluxes kick in around 100° C or 212° F), flux is a very reactive element that wants to bind with oxygen molecules. It is so reactive it can strip oxygen molecules that have already bonded with copper. So, it converts copper oxide back into basic copper. The second thing flux does is lower the surface tension of the solder. This lets the solder flow over the soldered surface, spread, and adhere.
Under a correctly controlled process, the flux is given some time to activate and do its work before solder is applied. Wave solder machines apply warm flux to the board first, then let it soak for a few seconds as the conveyor moves over a warming plate, and finally the flux is fully activated. The board then passes through the solder wave where the flux totally evaporates and essential leaves behind a clean board.
Solder paste works in a similar way. When conducting reflow processes, you have a ramp up to flux activation, a hold phase to let the flux do its work and evaporate, and finally, a ramp up to liquid phase where the solder melts and flows on the remaining flux. In theory, if reflow operations are done correctly, there should be minimal flux residue and board washing is simple or may not be required at all.
Boards that have been reworked (e.g., manually touching one individual component) will have residue and require washing with flux removers. The flux in solder wire is a different composition than the flux found in pens or liquid form. The flux in solder wire is dry powder and is more aggressive than paste as it has a shorter time to do its work.
Plus, there are specially formulated fluxes like the gel fluxes or tacky fluxes. These are formulated for the rework process, and the practice is to use a lot of it; so much of it that there is excessive residue and you need to remove it. The same goes for pen fluxes, which are also for rework. Most fluxes for wave soldering come in a 55-gallon drum, which is not something most end-users keep on the workbench!
When it comes to technical cleaning, ACL Staticide manufactures top-quality rework and repair cleaning products and compliments, and QSource.com is your resource for all of them.
Thank you Steve, for that informative Guest Blog and for clearing up those flux cleaning myths. We look forward to your next blog submission.
For information about ACL Staticide and their related products, please visit our ACL Staticide Department at QSource.com. You may also contact us via email or phone at 800-966-6020 and one of our associates will be happy to assist you.
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Steve Allen's Previous Guest Blogs
- An Update on the HCFC-225 (AK-225) Phase Out & Ban – Guest Blog
- More About the Basics of Flux in Electronics Soldering – Guest Blog
- Focusing on Sustainability in Chemical Processing & Product Development – Guest Blog
- Strength of a Cleaning Solvent – Kauri-Butanol Values & Solvent Solubility – Guest Blog
- Volatile Organic Compounds & Evolving Regulations – Guest Blog
- Use Proper Balance to Create an Efficient, Cost-Effective PCB Cleaning Process - Guest Blog
- Why Clean "No Cleans?" Printed Circuit Board Flux Removal – Guest Blog
- How to Use the 80:20 Rule to Focus on the Business Innovation Process - Guest Blog